Silsesquioxane nano-particles used for modifying properties of polymer hydrogels, and used to control X-ray contrasts. A combined X-ray and neutron scattering study

Kell Mortensen, Annaka Masahiko

研究成果: Contribution to journalArticle

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Organic-inorganic hybrid materials can be tailored to combine the advantages of organic polymers with those of inorganic components. An example is the design of a composite material obeying specific mecha-nical properties, light transmission factors and refractive index that makes it suitable for implant as intraocular lens. We have with this purpose studied a composite material composed of hydrophobically-modified poly(ethylene glycol) (HM-PEG) and polyhedral oligomeric silsesquio-xane (OCAPS) nano-particles, using combined neutron and X-ray scattering methods (SANS and SAXS). The OCAPS nano-particles are very well dispersed within water as well as within the polymer gel structure. The dispersion characteristics remain unchanged upon loading into the micellar structure, but the different contrasts factors of SANS and SAXS unambiguously show that OCAPS nano-particles are located within the whole gel-phase, except the micellar cores. The ideal dispersion within the aqueous phase makes silsesquioxane molecules ideal for controlled variation of the X-ray contrasts in small-angle X-ray scattering experiments as well as in X-ray imaging.

元の言語英語
ページ(範囲)3353-3360
ページ数8
ジャーナルColloid and Polymer Science
293
発行部数11
DOI
出版物ステータス出版済み - 11 1 2015

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Colloid and Surface Chemistry
  • Materials Chemistry

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