Single- and double-cations borohydrides for hydrogen storage applications

Shin Ichi Orimo, Yuko Nakamori, Haiwen Li, Motoaki Matsuo, Toyoto Sato, Nobuko Ohba, Kazutoshi Miwa, Shin Ichi Towata

研究成果: 著書/レポートタイプへの貢献会議での発言

1 引用 (Scopus)

抄録

The thermal desorption temperature Td of single-cation borohydrides was found to decrease with increasing the value of the Pauling electronegativity χP of the cation (metal). We examined T d of double-cation borohydrides ZrLin-4(BH 4)n, and then the correlation between Td and χP determined for single-cation borohydrides is extended to double-cation ones. Td for ZrLin-4(BH4) n with the composition n from 4 to 6 continuously increases from 440 K to 650 K, and approaches that of LiBH4, 740 K: Td correlates with the averaged χP calculated from n. The extended correlation might lead to precise adjustments in the thermodynamical stabilities of borohydrides.

元の言語英語
ホスト出版物のタイトルMaterials Issues in a Hydrogen Economy - Proceedings of the International Symposium
出版者World Scientific Publishing Co. Pte Ltd
ページ124-129
ページ数6
ISBN(印刷物)9812838015, 9789812838018
出版物ステータス出版済み - 1 1 2009
イベント2007 International Symposium on Materials Issues in a Hydrogen Economy - Richmond, VA, 米国
継続期間: 11 12 200711 15 2007

出版物シリーズ

名前Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium

その他

その他2007 International Symposium on Materials Issues in a Hydrogen Economy
米国
Richmond, VA
期間11/12/0711/15/07

Fingerprint

Borohydrides
Hydrogen storage
Cations
Positive ions
Electronegativity
Thermal desorption
Metals
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials

これを引用

Orimo, S. I., Nakamori, Y., Li, H., Matsuo, M., Sato, T., Ohba, N., ... Towata, S. I. (2009). Single- and double-cations borohydrides for hydrogen storage applications. : Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium (pp. 124-129). (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium). World Scientific Publishing Co. Pte Ltd.

Single- and double-cations borohydrides for hydrogen storage applications. / Orimo, Shin Ichi; Nakamori, Yuko; Li, Haiwen; Matsuo, Motoaki; Sato, Toyoto; Ohba, Nobuko; Miwa, Kazutoshi; Towata, Shin Ichi.

Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. World Scientific Publishing Co. Pte Ltd, 2009. p. 124-129 (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium).

研究成果: 著書/レポートタイプへの貢献会議での発言

Orimo, SI, Nakamori, Y, Li, H, Matsuo, M, Sato, T, Ohba, N, Miwa, K & Towata, SI 2009, Single- and double-cations borohydrides for hydrogen storage applications. : Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium, World Scientific Publishing Co. Pte Ltd, pp. 124-129, 2007 International Symposium on Materials Issues in a Hydrogen Economy, Richmond, VA, 米国, 11/12/07.
Orimo SI, Nakamori Y, Li H, Matsuo M, Sato T, Ohba N その他. Single- and double-cations borohydrides for hydrogen storage applications. : Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. World Scientific Publishing Co. Pte Ltd. 2009. p. 124-129. (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium).
Orimo, Shin Ichi ; Nakamori, Yuko ; Li, Haiwen ; Matsuo, Motoaki ; Sato, Toyoto ; Ohba, Nobuko ; Miwa, Kazutoshi ; Towata, Shin Ichi. / Single- and double-cations borohydrides for hydrogen storage applications. Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium. World Scientific Publishing Co. Pte Ltd, 2009. pp. 124-129 (Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium).
@inproceedings{c9e18db16663453998ffe581788779dc,
title = "Single- and double-cations borohydrides for hydrogen storage applications",
abstract = "The thermal desorption temperature Td of single-cation borohydrides was found to decrease with increasing the value of the Pauling electronegativity χP of the cation (metal). We examined T d of double-cation borohydrides ZrLin-4(BH 4)n, and then the correlation between Td and χP determined for single-cation borohydrides is extended to double-cation ones. Td for ZrLin-4(BH4) n with the composition n from 4 to 6 continuously increases from 440 K to 650 K, and approaches that of LiBH4, 740 K: Td correlates with the averaged χP calculated from n. The extended correlation might lead to precise adjustments in the thermodynamical stabilities of borohydrides.",
author = "Orimo, {Shin Ichi} and Yuko Nakamori and Haiwen Li and Motoaki Matsuo and Toyoto Sato and Nobuko Ohba and Kazutoshi Miwa and Towata, {Shin Ichi}",
year = "2009",
month = "1",
day = "1",
language = "English",
isbn = "9812838015",
series = "Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium",
publisher = "World Scientific Publishing Co. Pte Ltd",
pages = "124--129",
booktitle = "Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium",
address = "Singapore",

}

TY - GEN

T1 - Single- and double-cations borohydrides for hydrogen storage applications

AU - Orimo, Shin Ichi

AU - Nakamori, Yuko

AU - Li, Haiwen

AU - Matsuo, Motoaki

AU - Sato, Toyoto

AU - Ohba, Nobuko

AU - Miwa, Kazutoshi

AU - Towata, Shin Ichi

PY - 2009/1/1

Y1 - 2009/1/1

N2 - The thermal desorption temperature Td of single-cation borohydrides was found to decrease with increasing the value of the Pauling electronegativity χP of the cation (metal). We examined T d of double-cation borohydrides ZrLin-4(BH 4)n, and then the correlation between Td and χP determined for single-cation borohydrides is extended to double-cation ones. Td for ZrLin-4(BH4) n with the composition n from 4 to 6 continuously increases from 440 K to 650 K, and approaches that of LiBH4, 740 K: Td correlates with the averaged χP calculated from n. The extended correlation might lead to precise adjustments in the thermodynamical stabilities of borohydrides.

AB - The thermal desorption temperature Td of single-cation borohydrides was found to decrease with increasing the value of the Pauling electronegativity χP of the cation (metal). We examined T d of double-cation borohydrides ZrLin-4(BH 4)n, and then the correlation between Td and χP determined for single-cation borohydrides is extended to double-cation ones. Td for ZrLin-4(BH4) n with the composition n from 4 to 6 continuously increases from 440 K to 650 K, and approaches that of LiBH4, 740 K: Td correlates with the averaged χP calculated from n. The extended correlation might lead to precise adjustments in the thermodynamical stabilities of borohydrides.

UR - http://www.scopus.com/inward/record.url?scp=84903732039&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84903732039&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:84903732039

SN - 9812838015

SN - 9789812838018

T3 - Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium

SP - 124

EP - 129

BT - Materials Issues in a Hydrogen Economy - Proceedings of the International Symposium

PB - World Scientific Publishing Co. Pte Ltd

ER -