Single crystal growth and electronic state of new compounds RPt2Cd20(R = La-Nd, Sm)

Hiroshi Doto, Yusuke Hirose, Fuminori Honda, Tetsuya Takeuchi, Yoshinori Haga, Rikio Settai

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

We succeeded in growing five new single crystalline compounds RPt2Cd20(R = La, Ce, Pr, Nd, and Sm) by the Cd self-flux method. These compounds are found to crystallize in the cubic CeCr2Al20-type crystal structure by the X-ray diffraction using single crystals. We measured the electrical resistivity, magnetic properties, and specific heat for all compounds. The resistivity for R = Ce, Nd, and Sm indicates an abrupt decrease, which might correspond to a magnetic transition. It is suggested that the ground state of CePt2Cd20is Γ7doublet from the magnetization measurement. The magnetization of PrPt2Cd20shows a metamagnetic behavior at 1.6 T in the paramagnetic state, which could be due to the crystalline electric field effect with non-Kramers Γ3doublet or Γ1singlet ground state. The contribution of optical phonon modes to the lattice specific heat is discussed in LaPt2Cd20.

本文言語英語
ページ(範囲)332-338
ページ数7
ジャーナルJournal of Alloys and Compounds
693
DOI
出版ステータス出版済み - 2017
外部発表はい

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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