遷移金属カチオンを用いたイオン交換によるNaCo_2O_4のサイト選択元素置換

Yoshihiro Nojiri, Michitaka Ohtaki

    研究成果: ジャーナルへの寄稿記事

    抄録

    Incorporation of Ni ions into two different sites of the Na and Co sites of NaCo_2O_4 was carried out by the processes of conventional elemental substitution for Co ion and solid state ion exchange of mobile Na^+ ion. The changes of the lattice parameters of "substituted" and "exchanged" samples were different, suggesting that the Ni ions occupy different sites. The Ni-substituted sample for Co showed a significant decrease of Seebeck coefficient keeping the electrical conductivity almost intact, while Ni-exchanged samples for Na showed a lower electrical conductivity than that of the non-substituted sample with keeping the Seebeck coefficient unchanged. These results suggest that Ni cations introduced to the Co site decouples the Co-Co spin exchange, whereas those at the Na site compensates positive holes by providing conduction electrons.
    元の言語Japanese
    ページ(範囲)400-404
    ページ数5
    ジャーナルJournal of the Ceramic Society of Japan
    113
    発行部数1318
    DOI
    出版物ステータス出版済み - 6 1 2005

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    Transition metals
    Cations
    Ion exchange
    Substitution reactions
    Ions
    Seebeck coefficient
    Lattice constants
    Electrons
    Electric Conductivity

    これを引用

    遷移金属カチオンを用いたイオン交換によるNaCo_2O_4のサイト選択元素置換. / Nojiri, Yoshihiro; Ohtaki, Michitaka.

    :: Journal of the Ceramic Society of Japan, 巻 113, 番号 1318, 01.06.2005, p. 400-404.

    研究成果: ジャーナルへの寄稿記事

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    abstract = "Incorporation of Ni ions into two different sites of the Na and Co sites of NaCo_2O_4 was carried out by the processes of conventional elemental substitution for Co ion and solid state ion exchange of mobile Na^+ ion. The changes of the lattice parameters of {"}substituted{"} and {"}exchanged{"} samples were different, suggesting that the Ni ions occupy different sites. The Ni-substituted sample for Co showed a significant decrease of Seebeck coefficient keeping the electrical conductivity almost intact, while Ni-exchanged samples for Na showed a lower electrical conductivity than that of the non-substituted sample with keeping the Seebeck coefficient unchanged. These results suggest that Ni cations introduced to the Co site decouples the Co-Co spin exchange, whereas those at the Na site compensates positive holes by providing conduction electrons.",
    author = "Yoshihiro Nojiri and Michitaka Ohtaki",
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    AU - Nojiri, Yoshihiro

    AU - Ohtaki, Michitaka

    PY - 2005/6/1

    Y1 - 2005/6/1

    N2 - Incorporation of Ni ions into two different sites of the Na and Co sites of NaCo_2O_4 was carried out by the processes of conventional elemental substitution for Co ion and solid state ion exchange of mobile Na^+ ion. The changes of the lattice parameters of "substituted" and "exchanged" samples were different, suggesting that the Ni ions occupy different sites. The Ni-substituted sample for Co showed a significant decrease of Seebeck coefficient keeping the electrical conductivity almost intact, while Ni-exchanged samples for Na showed a lower electrical conductivity than that of the non-substituted sample with keeping the Seebeck coefficient unchanged. These results suggest that Ni cations introduced to the Co site decouples the Co-Co spin exchange, whereas those at the Na site compensates positive holes by providing conduction electrons.

    AB - Incorporation of Ni ions into two different sites of the Na and Co sites of NaCo_2O_4 was carried out by the processes of conventional elemental substitution for Co ion and solid state ion exchange of mobile Na^+ ion. The changes of the lattice parameters of "substituted" and "exchanged" samples were different, suggesting that the Ni ions occupy different sites. The Ni-substituted sample for Co showed a significant decrease of Seebeck coefficient keeping the electrical conductivity almost intact, while Ni-exchanged samples for Na showed a lower electrical conductivity than that of the non-substituted sample with keeping the Seebeck coefficient unchanged. These results suggest that Ni cations introduced to the Co site decouples the Co-Co spin exchange, whereas those at the Na site compensates positive holes by providing conduction electrons.

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    JO - Journal of the Ceramic Society of Japan

    JF - Journal of the Ceramic Society of Japan

    SN - 1882-1022

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