Slow Magnetic Relaxation in a Mononuclear Ruthenium(III) Complex

Shu Qi Wu, Yuji Miyazaki, Motohiro Nakano, Sheng Qun Su, Zi Shuo Yao, Hui Zhong Kou, Osamu Sato

研究成果: ジャーナルへの寄稿学術誌査読

21 被引用数 (Scopus)

抄録

The development of magnetic molecules with long spin reversal/decoherence times highly depends on the understanding of relaxation behavior under different external conditions. Herein, a magnetic study on a RuIII complex (1) is presented. Detailed analysis of the relaxation time and the magneto-heat capacity data suggests that the resonant phonon trapping process dominates the magnetic relaxation in the crystalline sample of 1, slowing down the spin relaxation rate, as further confirmed by the measurements on a ground sample and frozen solution. Thus, it provides a rare example showing that 4d metal-centered mononuclear compounds without second-order anisotropy can display slow magnetic relaxation.

本文言語英語
ページ(範囲)10028-10033
ページ数6
ジャーナルChemistry - A European Journal
23
42
DOI
出版ステータス出版済み - 7月 26 2017

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 有機化学

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