Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications

Rajendran Prabakaran, Shaji Sidney, Dhasan Mohan Lal, C. Selvam, Sivasankaran Harish

    研究成果: Contribution to journalArticle査読

    16 被引用数 (Scopus)

    抄録

    In this work, we experimentally investigated the solidification behavior of functionalized graphene-based phase change nanocomposites inside a sphere. The influence of graphene nanoplatelets on thermal transport and rheological characteristics of the such nanocomposites were also discussed. We adopted the covalent functionalization method to prepare highly stable phase change nanocomposites using commercially available phase change material (PCM) OM08 as the host matrix and graphene nanoplatelets (GnPs) with 0.1, 0.3, and 0.5 volume percentage as the nano inclusions. We report a maximum thermal conductivity enhancement of ~102 and ~46% with 0.5 vol% in the solid and liquid states, respectively. Rheological measurements show that the pure PCM shows Newtonian behavior, whereas the inclusion of GnPs leads to the transition to non-Newtonian behavior, especially at lower shear rates. Viscosity of the nanocomposite increases with an increase in the volume fraction of GnP. For 0.5 vol% of GnPs, maximum increase in viscosity was found to be ~37% at a shear rate of 1000 s−1. Time required for complete solidification decreases with the loading of GnPs. Maximum reduction in solidification time with 0.5 vol% of GnPs was ~40% for bath temperature of −10C.

    本文言語英語
    論文番号3473
    ジャーナルEnergies
    12
    18
    DOI
    出版ステータス出版済み - 9 9 2019

    All Science Journal Classification (ASJC) codes

    • 再生可能エネルギー、持続可能性、環境
    • エネルギー工学および電力技術
    • エネルギー(その他)
    • 制御と最適化
    • 電子工学および電気工学

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