Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide

Hidenori Higashi, Yoshio Iwai, Yasuhiko Arai

研究成果: ジャーナルへの寄稿総説査読

58 被引用数 (Scopus)

抄録

A brief introduction of the data sources and the applications of correlation methods for the solubilities and diffusion coefficients of hig-boiling compounds (mainly in solid state) in supercritical carbon dioxide are reviewed. Empirical equations, equations of state, solution models, and the Monte Carlo simulation for the calculation of solubilities in supercritical carbon dioxide are discussed. The application of empirical equation based on the Stokes-Einstein model, rough hard sphere theory, Schmidt number correlation, and molecular dynamics simulation for the calculation of diffusion coefficients in supercritical carbon dioxide at infinite dilution condition are reviewed. Further, the application of the Darken equation and the Leffler and Cullinan equation for the calculation of concentration dependence of diffusion coefficients in supercritical carbon dioxide is presented.

本文言語英語
ページ(範囲)3027-3044
ページ数18
ジャーナルChemical Engineering Science
56
10
DOI
出版ステータス出版済み - 6月 12 2001

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)
  • 産業および生産工学

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