Solvated electrons on metal oxide surfaces

Jin Zhao, Bin Li, Ken Onda, Min Feng, Hrvoje Petek

研究成果: Contribution to journalReview article査読

120 被引用数 (Scopus)

抄録

Solvated electrons can be introduced into protic solvents through the dissolution of highly reducing species such as alkali metals or through the exposure of liquids to ionizing radiation. Molecular cluster anions provide a versatile environment where electron solvation can be studied through cluster-size selection over a range from the single molecule to the near-bulk solvent limits. TR-2PP has been used to study electron solvation for a variety of solvent molecule overlayers on metal surfaces including alkanes, alcohols, nitriles and water. On metal surfaces, the solvation dynamics are governed by the degree of crystallinity of ice and the electronic structure of the substrate. The two-dimensional solvated electrons at solvent surfaces may be particularly reactive metastable reagents that can participate in a variety of interfacial reactions.

本文言語英語
ページ(範囲)4402-4427
ページ数26
ジャーナルChemical Reviews
106
10
DOI
出版ステータス出版済み - 10 1 2006
外部発表はい

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント 「Solvated electrons on metal oxide surfaces」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル