Sonication assisted rehydration of hydrotalcite catalyst for isomerization of glucose to fructose

Gihoon Lee, Yeojin Jeong, Atsushi Takagaki, Ji Chul Jung

研究成果: Contribution to journalArticle査読

40 被引用数 (Scopus)


A series of hydrotalcite catalysts, including mother hydrotalcite (HT-M), calcined hydrotalcite (HT-C), and rehydrated hydrotalcites (HT-RM and HT-RSX) were prepared for isomerization of glucose to fructose. Two types of rehydration methods such as mechanical stirring method and sonication assisted method were employed for rehydration of hydrotalcite. Structure of hydrotalcite was successfully recovered to a layered double hydroxide structure via two rehydration processes (Memory effect of hydrotalcite). All rehydrated hydrotalcites (HT-RSX) with a sonication assisted method exhibited a higher fructose yield than rehydrated hydrotalcite (HT-RM) with a vigorous mechanical stirring in this reaction. In consideration of catalytic activity and rehydration time, sonication rather than mechanical stirring played an efficient role to improve catalytic activity of hydrotalcite in this reaction. Characterization results clearly revealed that the enhanced catalytic activity of HT-RSX catalyst was due to its abundant surface weak base sites resulted from a facile vertical breaking and exfoliation of hydrotalcite layers during the sonication assisted rehydration process. Yield for fructose over rehydrated hydrotalcite catalysts showed a tendency to increase with decreasing the crystallite size of catalyst and with increasing the weak base sites of catalyst. Among the catalysts tested, HT-RS10 with the smallest crystallite size and the largest weak base sites exhibited the highest fructose yield in this reaction.

ジャーナルJournal of Molecular Catalysis A: Chemical
出版ステータス出版済み - 11 1 2014

All Science Journal Classification (ASJC) codes

  • 触媒
  • プロセス化学およびプロセス工学
  • 物理化学および理論化学


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