Specific Intermolecular Interactions by the Localized π-Electrons in C70-fullerene

Takuya Kubo, Eisuke Kanao, Takatoshi Matsumoto, Toyohiro Naito, Tomoharu Sano, Mingdi Yan, Koji Otsuka

研究成果: Contribution to journalArticle査読

7 被引用数 (Scopus)

抄録

We report the specific intermolecular interactions on C70-fullerene. A newly developed silica-monolithic capillary column, which was modified with C70-fullerene via a particular thermal reactive molecule, perfluorophenyl azide, provided a selective retention behavior toward polycyclic aromatic hydrocarbons in liquid chromatography. Especially, a hemispherical molecule, i. e., corannulene, was significantly retained on this C70-fullerene column. Results of the computer simulation of the molecules suggested that the specific interaction might be caused by the deflection of the π-electrons-density in C70-fullerene. Furthermore, the absorption spectrometry also indicated that the absorption spectra of C70-fullerene with/without corannulene were dramatically changed by the specific interaction, whereas no spectrum differences were observed with C60-fullerene.

本文言語英語
ページ(範囲)5900-5904
ページ数5
ジャーナルChemistrySelect
1
18
DOI
出版ステータス出版済み - 11 1 2016
外部発表はい

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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