Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation

Yutaka Hisamune, Keiichi Nishimura, Koji Isakari, Masatoshi Ishida, Shigeki Mori, Satoru Karasawa, Tatsuhisa Kato, Sangsu Lee, Dongho Kim, Hiroyuki Furuta

研究成果: Contribution to journalArticle査読

36 被引用数 (Scopus)

抄録

A contracted doubly N-confused dioxohexaphyrin derivative served as a dinucleating metal ligand for unsymmetrical coordination. The complexation of two palladium(II) cations led to the formation of π-radical species that were persistent in atmospheric air in the presence of moisture. Effective delocalization of an unpaired electron over the hexaphyrin backbone could contribute to the distinct chemical stability.

本文言語英語
ページ(範囲)7323-7327
ページ数5
ジャーナルAngewandte Chemie - International Edition
54
25
DOI
出版ステータス出版済み - 6 1 2015

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

フィンガープリント 「Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル