Stable Sulfur Ylides. X. Reactions of Carbonyl-Stabilized Sulfonium Ylides with Acetyl Chloride

Sunao Furukawa, Jun etsu Igarashi, Mitsuaki Watanabe, Toshio Kinoshita

研究成果: ジャーナルへの寄稿記事

5 引用 (Scopus)

抜粋

Highly stabilized sulfonium diacetylmethylides (la—c) reacted with acetyl chloride to give a mixture of the enol acetates (2a—c) and the enol diacetates (3a—c). Similarly, sulfonium acetylcarbomethoxymethylides (5a, b) gave the enol acetates (6a, b). These enol acetates were hydrolyzed with HCl-MeOH to give 3-methylthio-(3-phenylthio-)2, 4-pentanediones (4a, b) or methyl 2-methylthio-(2-phenylthio-)acetoacetates (7a, b).

元の言語英語
ページ(範囲)227-229
ページ数3
ジャーナルChemical and Pharmaceutical Bulletin
38
発行部数1
DOI
出版物ステータス出版済み - 1 1 1990
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Drug Discovery

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