Stereochemical features of the [1,2]-Wittig rearrangement of O- glycosides derived from D-galactono- and D-xylono-γ-lactones: A new approach to the core part of zaragozic acids

Katsuhiko Tomooka, M. Kikuchi, Kazunobu Igawa, P. H. Keong, T. Nakai

研究成果: Contribution to journalArticle査読

19 被引用数 (Scopus)

抄録

The Wittig rearrangement of D-galactono-γ-lactone derived β-O- glycoside is shown to afford β-C-glycoside (retention product), a potentially useful intermediate for zaragozic acid synthesis. By contrast, the rearrangement of the D-xylonolactone-derived counterpart was found to violate the retention principle to yield an inversion product as the major product.

本文言語英語
ページ(範囲)1917-1920
ページ数4
ジャーナルTetrahedron Letters
40
10
DOI
出版ステータス出版済み - 3 5 1999
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

フィンガープリント 「Stereochemical features of the [1,2]-Wittig rearrangement of O- glycosides derived from D-galactono- and D-xylono-γ-lactones: A new approach to the core part of zaragozic acids」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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