Stereochemistry and Reactions of Aziridinyl-phosphinothionates Derived from Amino Acids

Akinori Hirashima, Morifusa Eto

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

Aziridinylphosphinothionates were prepared from optically active ethyl hydrogen phenylphos-phonothionates and l-bromo-2-alkanamines derived from leucine or valine. The aziridine ring was opened by the action of some nucleophiles. Refluxing the aziridinylphosphinothionates in acetone with sodium iodide caused hydrolysis accompanied by the rearrangement of the sulfur atom to give β-mercaptoethylphosphonamidates. The reaction mechanism was discussed with stereochemical considerations. The insecticidal activity of the products was also examined.

本文言語英語
ページ(範囲)829-838
ページ数10
ジャーナルAgricultural and Biological Chemistry
47
4
DOI
出版ステータス出版済み - 1 1983

All Science Journal Classification (ASJC) codes

  • 生化学、遺伝学、分子生物学(全般)
  • 農業および生物科学(全般)

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