Stereodivergent direct catalytic asymmetric mannich-type reactions of α-isothiocyanato ester with ketimines

Gang Lu, Tatsuhiko Yoshino, Hiroyuki Morimoto, Shigeki Matsunaga, Masakatsu Shibasaki

研究成果: ジャーナルへの寄稿記事

113 引用 (Scopus)

抜粋

Now accessible: Sterically hindered vicinal tetrasubstituted carbon stereocenters, which are not accessible by asymmetric hydrogenation, were constructed by a catalytic asymmetric C-C bond formation (see scheme; Dpp=diphenylphosphinoyl). By changing the Group 2 metal center, stereodivergent access to α,β-tetrasubstituted α,β-diamino esters was realized.

元の言語英語
ページ(範囲)4382-4385
ページ数4
ジャーナルAngewandte Chemie - International Edition
50
発行部数19
DOI
出版物ステータス出版済み - 5 2 2011
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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