Stereospecific polymerization with PMMA binding peptide

Kun Zhang; Yusuke Hosaka; Hisao Matsuno; Takeshi Serizawa

Stereospecific polymerization with PMMA binding peptide

Kun Zhang, Yusuke Hosaka, Hisao Matsuno, Takeshi Serizawa

研究成果: 会議への寄与タイプ › 学会誌 › 査読

抄録

Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)₂, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

本文言語	英語
ページ	716
ページ数	1
出版ステータス	出版済み - 2006
外部発表	はい
イベント	55th SPSJ Annual Meeting - Nagoya, 日本継続期間: 5月 24 2006 → 5月 26 2006

その他

その他	55th SPSJ Annual Meeting
国/地域	日本
City	Nagoya
Period	5/24/06 → 5/26/06

!!!All Science Journal Classification (ASJC) codes

工学（全般）

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title = "Stereospecific polymerization with PMMA binding peptide",

abstract = "Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.",

author = "Kun Zhang and Yusuke Hosaka and Hisao Matsuno and Takeshi Serizawa",

year = "2006",

language = "English",

pages = "716",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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TY - CONF

T1 - Stereospecific polymerization with PMMA binding peptide

AU - Zhang, Kun

AU - Hosaka, Yusuke

AU - Matsuno, Hisao

AU - Serizawa, Takeshi

PY - 2006

Y1 - 2006

N2 - Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

AB - Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

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UR - http://www.scopus.com/inward/citedby.url?scp=33749676649&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33749676649

SP - 716

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Stereospecific polymerization with PMMA binding peptide

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!!!All Science Journal Classification (ASJC) codes

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