Stimuli-responsive folding and unfolding of a polymer bearing multiple cerium(IV) bis(porphyrinate) joints: Mechano-imitation of the action of a folding ruler

Masayuki Shibata, Satoshi Tanaka, Tomohiro Ikeda, Seiji Shinkai, Kenji Kaneko, Soichiro Ogi, Masayuki Takeuchi

研究成果: ジャーナルへの寄稿学術誌査読

22 被引用数 (Scopus)

抄録

A pivotal guest role: A new porphyrin polymer, poly(PorZn·DD) (see picture, pink/purple), composed of a porphyrinatozinc and a porphyrin double-decker complex as a repeating unit was synthesized. In poly(PorZn·DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double-decker complexes and the polymer undergoes shortening and compaction.

本文言語英語
ページ(範囲)397-400
ページ数4
ジャーナルAngewandte Chemie - International Edition
52
1
DOI
出版ステータス出版済み - 1月 2 2013

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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