Structure and magnetism of a trinuclear CuII-GdIII-CuII complex derived from one-pot reaction with 2,6-di(acetoacetyl)pyridine

Takuya Shiga, Masaaki Ohba, Hisashi Okawa

研究成果: Contribution to journalArticle査読

53 被引用数 (Scopus)

抄録

A unique 3d-4f mixed metal trinuclear compound, [Cu2Gd(L)2(NO3)2]NO3 (1; H2L = 2,6-di(acetoacetyl)pyridine), is derived from a 'one-pot' reaction with H2L, Cu(NO3)2 · 3H2O and Gd(NO3)3 · 5H2O. Two L2- providing one central 2,6-diacylpyridine site and two terminal 1,3-diketonate sites hold two CuII ions and GdIII ion and form a linear Cu-Gd-Cu trinuclear core. This compound shows ferromagnetic interaction between CuII and GdIII.

本文言語英語
ページ(範囲)15-18
ページ数4
ジャーナルInorganic Chemistry Communications
6
1
DOI
出版ステータス出版済み - 1 1 2003

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

フィンガープリント 「Structure and magnetism of a trinuclear Cu<sup>II</sup>-Gd<sup>III</sup>-Cu<sup>II</sup> complex derived from one-pot reaction with 2,6-di(acetoacetyl)pyridine」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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