Study of RuNi/TiO2 catalysts for selective CO methanation

Shohei Tada, Ryuji Kikuchi, Atsushi Takagaki, Takashi Sugawara, S. Ted Oyama, Kohei Urasaki, Shigeo Satokawa

研究成果: ジャーナルへの寄稿学術誌査読

83 被引用数 (Scopus)

抄録

The removal of CO from reformate streams by selective CO methanation was investigated over TiO2 supported RuNi bimetallic and monometallic catalysts. The combination of Ru and Ni enhanced CO methanation at low temperatures. The introduction of Ni into Ru/TiO2 decreased the CO2 conversion rate at 260°C from 10 to 7.3μmolmin-1gcat-1. The use of Ru and Ni, thus, expands the temperature range of selective CO methanation. Transmission electron microscopy and temperature programmed reduction by H2 confirmed that Ru species were in close proximity to Ni species on RuNi/TiO2, indicating a decrease in direct contact between Ru and TiO2. Fourier transform infrared spectroscopy techniques revealed that the decomposition of the formate species, formed during CO2 methanation, is slow over RuNi/TiO2, in contrast to Ru/TiO2.

本文言語英語
ページ(範囲)258-264
ページ数7
ジャーナルApplied Catalysis B: Environmental
140-141
DOI
出版ステータス出版済み - 8月 2013
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 環境科学(全般)
  • プロセス化学およびプロセス工学

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