2H NMR study of hydrogen bonding in deuterated kaolinite

Shigenobu Hayashi; Etsuo Akiba; Ritsuro Miyawaki; Shinji Tomura

doi:10.1346/CCMN.1994.0420507

²H NMR study of hydrogen bonding in deuterated kaolinite

Shigenobu Hayashi, Etsuo Akiba, Ritsuro Miyawaki, Shinji Tomura

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

5 被引用数 (Scopus)

抄録

²H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

本文言語	英語
ページ（範囲）	561-566
ページ数	6
ジャーナル	Clays and Clay Minerals
巻	42
号	5
DOI	https://doi.org/10.1346/CCMN.1994.0420507
出版ステータス	出版済み - 10月 1994
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

水の科学と技術
土壌科学
地球化学および岩石学
地球惑星科学（その他）

文献へのアクセス

10.1346/CCMN.1994.0420507

他のファイルとリンク

引用スタイル

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title = "2H NMR study of hydrogen bonding in deuterated kaolinite",

abstract = "2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak",

author = "Shigenobu Hayashi and Etsuo Akiba and Ritsuro Miyawaki and Shinji Tomura",

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N2 - 2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

AB - 2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

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