Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

Gang Xu; Kazuya Otsubo; Teppei Yamada; Shun Sakaida; Hiroshi Kitagawa

doi:10.1021/ja402727d

Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

Gang Xu, Kazuya Otsubo, Teppei Yamada, Shun Sakaida, Hiroshi Kitagawa

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

257 被引用数 (Scopus)

抄録

The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.

本文言語	英語
ページ（範囲）	7438-7441
ページ数	4
ジャーナル	Journal of the American Chemical Society
巻	135
号	20
DOI	https://doi.org/10.1021/ja402727d
出版ステータス	出版済み - 5月 22 2013
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja402727d

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abstract = "The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.",

author = "Gang Xu and Kazuya Otsubo and Teppei Yamada and Shun Sakaida and Hiroshi Kitagawa",

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T1 - Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

AU - Xu, Gang

AU - Otsubo, Kazuya

AU - Yamada, Teppei

AU - Sakaida, Shun

AU - Kitagawa, Hiroshi

PY - 2013/5/22

Y1 - 2013/5/22

N2 - The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.

AB - The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.

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Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

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!!!All Science Journal Classification (ASJC) codes

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