Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films

Jingxin Zhou, Tifeng Jiao, Adan Li, Yuanyuan Xing

研究成果: Chapter in Book/Report/Conference proceedingConference contribution

抜粋

Functional luminol derivative with cholesteryl substituted group has been designed and synthesized from the reaction of the corresponding precursor cholesteryl chloroformate with luminol. This compound can be spread on water surface to form stable monolayer. It has been found that UV and IR spectra confirmed the characteristic aromatic segment, imide group and cholesteryl substituted group. In addition, the CD spectra also showed positive CD signals, which may be attributed to the chiral cholesteryl substituted groups. AFM investigation indicated some aggregated domains with the averaged height about 3.6 ± 0.2 nm appeared. This suggested an organized structure of double molecules may be fabricated in the transferred LB films. The present results have demonstrated that the interfacial properties of luminol derivative can be modified by changing proper substituted groups of luminol, which show potential application in functional material fields such as ECL sensor.

元の言語英語
ホスト出版物のタイトルFrontiers of Materials, Chemical and Metallurgical Technologies
ページ176-179
ページ数4
エディション1
DOI
出版物ステータス出版済み - 11 28 2012
イベント2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012 - KunMing, 中国
継続期間: 10 12 201210 13 2012

出版物シリーズ

名前Advanced Materials Research
番号1
581-582
ISSN(印刷物)1022-6680

その他

その他2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012
中国
KunMing
期間10/12/1210/13/12

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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  • これを引用

    Zhou, J., Jiao, T., Li, A., & Xing, Y. (2012). Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. : Frontiers of Materials, Chemical and Metallurgical Technologies (1 版, pp. 176-179). (Advanced Materials Research; 巻数 581-582, 番号 1). https://doi.org/10.4028/www.scientific.net/AMR.581-582.176