Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films

Nao Hosaka, Sono Sasaki, Osami Sakata, Hideyuki Otsuka, Atsushi Takahara

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

Polyhedral oligomeric silsesquioxane (POSS), which is one of nanosized materials with a silica core and organic groups on the surface, meets increasing interest as building units for inorganic-organic hybrid materials. In this study, the molecular aggregation state of polystyrene (PS) based cyclopentyl-substituted POSS (CpPOSS) hybrid thin films are discussed. CpPOSS/PS hybrid thin films were prepared by spin-coating and annealed above the glass transition temperature. The structure of the hybrid films was investigated by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and grazing incidence X-ray diffraction (GIXD) measurements. Structural analyses revealed that CpPOSS segregated on the film surface and crystallized. The segregation of CpPOSS to the film surface was enhanced through annealing processes. The enrichment layer of CpPOSS, which can change the morphology and enrgetics of the films, seems to contribute to the thermal stability of the films.

元の言語英語
ホスト出版物のタイトル54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan
ページ3301-3302
ページ数2
54
エディション2
出版物ステータス出版済み - 2005
イベント54th SPSJ Symposium on Macromolecules - Yamagata, 日本
継続期間: 9 20 20059 22 2005

その他

その他54th SPSJ Symposium on Macromolecules
日本
Yamagata
期間9/20/059/22/05

Fingerprint

Crystalline materials
Thin films
Polymers
Polystyrenes
Hybrid materials
Spin coating
Atomic force microscopy
Thermodynamic stability
Agglomeration
X ray photoelectron spectroscopy
Silica
Annealing
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Hosaka, N., Sasaki, S., Sakata, O., Otsuka, H., & Takahara, A. (2005). Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films. : 54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan (2 版, 巻 54, pp. 3301-3302)

Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films. / Hosaka, Nao; Sasaki, Sono; Sakata, Osami; Otsuka, Hideyuki; Takahara, Atsushi.

54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan. 巻 54 2. 編 2005. p. 3301-3302.

研究成果: 著書/レポートタイプへの貢献会議での発言

Hosaka, N, Sasaki, S, Sakata, O, Otsuka, H & Takahara, A 2005, Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films. : 54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan. 2 Edn, 巻. 54, pp. 3301-3302, 54th SPSJ Symposium on Macromolecules, Yamagata, 日本, 9/20/05.
Hosaka N, Sasaki S, Sakata O, Otsuka H, Takahara A. Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films. : 54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan. 2 版 巻 54. 2005. p. 3301-3302
Hosaka, Nao ; Sasaki, Sono ; Sakata, Osami ; Otsuka, Hideyuki ; Takahara, Atsushi. / Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films. 54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan. 巻 54 2. 版 2005. pp. 3301-3302
@inproceedings{3989f6b3fd114365a4bfcba24ad42dcd,
title = "Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films",
abstract = "Polyhedral oligomeric silsesquioxane (POSS), which is one of nanosized materials with a silica core and organic groups on the surface, meets increasing interest as building units for inorganic-organic hybrid materials. In this study, the molecular aggregation state of polystyrene (PS) based cyclopentyl-substituted POSS (CpPOSS) hybrid thin films are discussed. CpPOSS/PS hybrid thin films were prepared by spin-coating and annealed above the glass transition temperature. The structure of the hybrid films was investigated by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and grazing incidence X-ray diffraction (GIXD) measurements. Structural analyses revealed that CpPOSS segregated on the film surface and crystallized. The segregation of CpPOSS to the film surface was enhanced through annealing processes. The enrichment layer of CpPOSS, which can change the morphology and enrgetics of the films, seems to contribute to the thermal stability of the films.",
author = "Nao Hosaka and Sono Sasaki and Osami Sakata and Hideyuki Otsuka and Atsushi Takahara",
year = "2005",
language = "English",
volume = "54",
pages = "3301--3302",
booktitle = "54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan",
edition = "2",

}

TY - GEN

T1 - Surface and interfacial structure of crystalline silsesquioxane nanofiller/polymer hybrid thin films

AU - Hosaka, Nao

AU - Sasaki, Sono

AU - Sakata, Osami

AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

PY - 2005

Y1 - 2005

N2 - Polyhedral oligomeric silsesquioxane (POSS), which is one of nanosized materials with a silica core and organic groups on the surface, meets increasing interest as building units for inorganic-organic hybrid materials. In this study, the molecular aggregation state of polystyrene (PS) based cyclopentyl-substituted POSS (CpPOSS) hybrid thin films are discussed. CpPOSS/PS hybrid thin films were prepared by spin-coating and annealed above the glass transition temperature. The structure of the hybrid films was investigated by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and grazing incidence X-ray diffraction (GIXD) measurements. Structural analyses revealed that CpPOSS segregated on the film surface and crystallized. The segregation of CpPOSS to the film surface was enhanced through annealing processes. The enrichment layer of CpPOSS, which can change the morphology and enrgetics of the films, seems to contribute to the thermal stability of the films.

AB - Polyhedral oligomeric silsesquioxane (POSS), which is one of nanosized materials with a silica core and organic groups on the surface, meets increasing interest as building units for inorganic-organic hybrid materials. In this study, the molecular aggregation state of polystyrene (PS) based cyclopentyl-substituted POSS (CpPOSS) hybrid thin films are discussed. CpPOSS/PS hybrid thin films were prepared by spin-coating and annealed above the glass transition temperature. The structure of the hybrid films was investigated by atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and grazing incidence X-ray diffraction (GIXD) measurements. Structural analyses revealed that CpPOSS segregated on the film surface and crystallized. The segregation of CpPOSS to the film surface was enhanced through annealing processes. The enrichment layer of CpPOSS, which can change the morphology and enrgetics of the films, seems to contribute to the thermal stability of the films.

UR - http://www.scopus.com/inward/record.url?scp=33645571755&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645571755&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33645571755

VL - 54

SP - 3301

EP - 3302

BT - 54th SPSJ Symposium on Macromolecules - Polymer Preprints, Japan

ER -