抄録
Interfacial thickness of surface mobile layer of polystyrene (PS) film below bulk glass transition temperature was studied. Uniformity of the bilayer interface, built from two surfaces of monodisperse PS (hPS) and monodisperse deuterated PS (dPS), was confirmed using atomic force microscopy. The interfacial broadening of the bilayer by annealing was examined on the basis of depth profiling by dynamic secondary ion mass spectroscopic (DSIMS) measurements. Interfacial thickness was found to monotically increase with annealing time at 393 K above bulk glass transition temperature. Results indicated constant interfacial thickness at temperatures between bulk glass transition temperature and surface glass transition temperature.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 6164-6166 |
| ページ数 | 3 |
| ジャーナル | Macromolecules |
| 巻 | 34 |
| 発行部数 | 18 |
| DOI | |
| 出版物ステータス | 出版済み - 8 28 2001 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
これを引用
Surface mobile layer of polystyrene film below bulk glass transition temperature [5]. / Kawaguchi, Daisuke; Tanaka, Keiji; Takahara, Atsushi; Kajiyama, Tisato.
：: Macromolecules, 巻 34, 番号 18, 28.08.2001, p. 6164-6166.研究成果: ジャーナルへの寄稿 › レター
}
TY - JOUR
T1 - Surface mobile layer of polystyrene film below bulk glass transition temperature [5]
AU - Kawaguchi, Daisuke
AU - Tanaka, Keiji
AU - Takahara, Atsushi
AU - Kajiyama, Tisato
PY - 2001/8/28
Y1 - 2001/8/28
N2 - Interfacial thickness of surface mobile layer of polystyrene (PS) film below bulk glass transition temperature was studied. Uniformity of the bilayer interface, built from two surfaces of monodisperse PS (hPS) and monodisperse deuterated PS (dPS), was confirmed using atomic force microscopy. The interfacial broadening of the bilayer by annealing was examined on the basis of depth profiling by dynamic secondary ion mass spectroscopic (DSIMS) measurements. Interfacial thickness was found to monotically increase with annealing time at 393 K above bulk glass transition temperature. Results indicated constant interfacial thickness at temperatures between bulk glass transition temperature and surface glass transition temperature.
AB - Interfacial thickness of surface mobile layer of polystyrene (PS) film below bulk glass transition temperature was studied. Uniformity of the bilayer interface, built from two surfaces of monodisperse PS (hPS) and monodisperse deuterated PS (dPS), was confirmed using atomic force microscopy. The interfacial broadening of the bilayer by annealing was examined on the basis of depth profiling by dynamic secondary ion mass spectroscopic (DSIMS) measurements. Interfacial thickness was found to monotically increase with annealing time at 393 K above bulk glass transition temperature. Results indicated constant interfacial thickness at temperatures between bulk glass transition temperature and surface glass transition temperature.
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U2 - 10.1021/ma010012k
DO - 10.1021/ma010012k
M3 - Letter
AN - SCOPUS:0035964512
VL - 34
SP - 6164
EP - 6166
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 18
ER -