Syntheses and reactions of multifunctional carbanions "ynolate anions"

研究成果: Contribution to journalArticle査読

25 被引用数 (Scopus)

抄録

Ynolates are carbanions having a triple bond in place of the double bond in enolate anions. Ynolates are ketene anion equivalents, thus ynolates introduce a ketene unit into substrates and the resulting products possess high reactivity. This allows ynolates to undergo unique reaction sequences. For the past 20 years, several methods for the generation of ynolates and their reactions have been developed. Recently, we have developed a highly efficient method for their generation and new rections such as olefination, tandem [2+2] cycloaddition-Dieckmann condensation, syntheses of β-lactams. In this review, an overview of the syntheses and the reactions of ynolates, especially focusing our recent results, are described.

本文言語英語
ページ(範囲)1155-1166
ページ数12
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
58
12
DOI
出版ステータス出版済み - 12 2000
外部発表はい

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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