Syntheses of all poasible calix[6]arene derivatives with MeO- and ROCOCH2O- substituents and their metal binding properties

Hideyuki Otsuka, Koji Araki, Seiji Shinkai

研究成果: Contribution to journalArticle査読

31 被引用数 (Scopus)

抄録

It has become possible to synthesize all possible calix[6]arene derivatives with MeO-and ROCOCH2O- substituents from corresponding O-methylated calix[6]arenes(2-7). The yields of these reactions were relatively high and the products could be easily purified because of the absence of other regioisomers. They are one mono-, three di-, three tri-, three tetra-, one penta-, and one hexa-EtOCOCH2O-substituted products. It was proved that O-methylation products act as useful basic skeletons to design functionalized calix[6]arenes with the desired number of ROCOCH2O substituents and the regioselectively-positioned ROCOCH2O groups.

本文言語英語
ページ(範囲)8757-8770
ページ数14
ジャーナルTetrahedron
51
32
DOI
出版ステータス出版済み - 8 7 1995

All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

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