Syntheses of metal-organic frameworks with protected phosphonate ligands

Teppei Yamada, Hiroshi Kitagawa

研究成果: ジャーナルへの寄稿学術誌査読

14 被引用数 (Scopus)

抄録

Protected phosphonate groups were embedded onto isophthalic acid and reacted with zinc ion to synthesize metal-organic frameworks (MOFs). Single-crystal X-ray diffraction measurement revealed the crystal structures of obtained MOFs under various temperatures and solvent conditions. The isopropyl groups were left protected when the complexation reaction was executed at 60 °C, while they were partially deprotected in the sample prepared at 120 °C. When the reaction was carried out at 180 °C, the isopropyl groups were totally deprotected. This result provides us with information on the deprotection reaction in a post-synthetic method for constructing MOFs.

本文言語英語
ページ(範囲)4148-4152
ページ数5
ジャーナルCrystEngComm
14
12
DOI
出版ステータス出版済み - 6月 21 2012
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

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