Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani, Shinya Nakayama, Mari Ichimura, Nobuhumi Nakamura, Yoshinori Naruta

研究成果: Contribution to journalArticle査読

12 被引用数 (Scopus)

抄録

Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.

本文言語英語
ページ(範囲)729-730
ページ数2
ジャーナルChemistry Letters
8
DOI
出版ステータス出版済み - 1 1 1999

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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