Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani; Shinya Nakayama; Mari Ichimura; Nobuhumi Nakamura; Yoshinori Naruta

doi:10.1246/cl.1999.729

Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani, Shinya Nakayama, Mari Ichimura, Nobuhumi Nakamura, Yoshinori Naruta

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

5 被引用数 (Scopus)

抄録

Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O₂ binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O₂) band at 578 cm^-1 in the resonance Raman spectrum.

本文言語	英語
ページ（範囲）	729-730
ページ数	2
ジャーナル	Chemistry Letters
号	8
DOI	https://doi.org/10.1246/cl.1999.729
出版ステータス	出版済み - 1999

!!!All Science Journal Classification (ASJC) codes

化学 (全般)

文献へのアクセス

10.1246/cl.1999.729

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引用スタイル

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abstract = "Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.",

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AU - Ichimura, Mari

AU - Nakamura, Nobuhumi

AU - Naruta, Yoshinori

PY - 1999

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AB - Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.

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