Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis

Takatoshi Muta, Hideyuki Otsuka, Atsushi Takahara

研究成果: 著書/レポートタイプへの貢献会議での発言

抄録

The authors report the hybridization of different olefin-containing polymers, chain-growth type polymer and step-growth type polymer, by olefin cross metathesis. An equal amount of olefin-containing polyester and 1,4-polybutadiene was mixed and dissolved in dichloromethane in the presence of Grubbs catalyst at room temperature. As the reaction proceeded, the melting endothermic peak of the hybrid polymer shifted to lower temperature. Finally, the melting peak was completely disappeared in DSC thermogram. The change in specific heat corresponding to the glass transition temperature of hybrid polymer was observed between each glass transition. These results indicate that the polymer scrambling reaction finally gives random copolymer consisted of butadiene unit and oligoester unit.

元の言語英語
ホスト出版物のタイトルPolymer Preprints, Japan - 55th SPSJ Annual Meeting
ページ193
ページ数1
55
エディション1
出版物ステータス出版済み - 2006
イベント55th SPSJ Annual Meeting - Nagoya, 日本
継続期間: 5 24 20065 26 2006

その他

その他55th SPSJ Annual Meeting
日本
Nagoya
期間5/24/065/26/06

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Olefins
Polymerization
Polymers
Melting
Polybutadienes
Dichloromethane
Butadiene
Specific heat
Polyesters
Glass transition
Copolymers
Temperature
Catalysts

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Muta, T., Otsuka, H., & Takahara, A. (2006). Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting (1 版, 巻 55, pp. 193)

Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. / Muta, Takatoshi; Otsuka, Hideyuki; Takahara, Atsushi.

Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 巻 55 1. 編 2006. p. 193.

研究成果: 著書/レポートタイプへの貢献会議での発言

Muta, T, Otsuka, H & Takahara, A 2006, Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 Edn, 巻. 55, pp. 193, 55th SPSJ Annual Meeting, Nagoya, 日本, 5/24/06.
Muta T, Otsuka H, Takahara A. Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. : Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 版 巻 55. 2006. p. 193
Muta, Takatoshi ; Otsuka, Hideyuki ; Takahara, Atsushi. / Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 巻 55 1. 版 2006. pp. 193
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