Synthesis and characterization of N-confused porphyrinatoantimony(V): Toward a low energy gap molecular wire

Takuji Ogawa, Hiroyuki Furuta, Minako Takahashi, Ayako Morino, Hidemitsu Uno

研究成果: Contribution to journalArticle査読

44 被引用数 (Scopus)

抄録

N-Confused tetraarylporphyrinatoantimony(V) dimethoxides were synthesized and their X-ray crystallographic structure, absorption spectra and voltammetric spectra were studied. X-ray crystallographic structure revealed neutral molecules with no counter anion. From the absorption spectra and voltammetric studies we estimated their energy gaps to be about 0.2 eV less than the corresponding porphyrinatoantimony(V). The axial ligands could easily be exchanged in solvent alcohol by acid promotion. These characteristics of N-confused porphyrinatoantimony(V) indicate that they are good candidates for the molecular wire component.

本文言語英語
ページ(範囲)551-557
ページ数7
ジャーナルJournal of Organometallic Chemistry
611
1-2
DOI
出版ステータス出版済み - 10 6 2000
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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