Synthesis and characterization of Na2Ti6O 13 whiskers and their transformation to (1-x) Na0.5Bi 0.5TiO3-xBaTiO3 ceramics

Deepam Maurya, M. Murayama, Shashank Priya

研究成果: Contribution to journalArticle査読

25 被引用数 (Scopus)

抄録

In this paper we report the synthesis of monoclinic Na2Ti 6O13 whiskers and their transformation to lead-free 0.93Na1/2Bi1/2TiO3-0.07BaTiO3 (NBTBT) ceramics. Synthesis of Na2Ti6O13 templates was performed using molten salt synthesis method. These whiskers were further characterized using XRD, SEM, TEM, and HR-TEM for structural analysis. Tape-casting method was used to align the whiskers in base matrix powder and subjected to various processing temperatures to elucidate the microstructure and texture evolution. For this, SEM, HR-TEM, AFM, and EDS analysis were used as principal tools. The sintering process can be understood by dividing it into three stages, namely (i) transformation of monoclinic whiskers in to NBTBT perovskite phase through topochemical reaction (<800°C), (ii) localized sintering confined on single whisker (800°-1050°C), and (iii) liquid-phase sintering as densification and grain growth occurs in the whole matrix (>1050°C). The concentric growth ledges observed on grain surfaces were found to be preferably confined on the corners of cubical grains indicating <111> growth direction. The Lotgering factor (f100) for the sintered matrix was found to decrease with increase in sintering temperature. The longitudinal piezoelectric constant (d33) of samples sintered for 20 h at 1175°, 1200°, and 1225°C was measured to be ∼153, ∼216, and ∼180 pC/N, respectively.

本文言語英語
ページ(範囲)2857-2871
ページ数15
ジャーナルJournal of the American Ceramic Society
94
9
DOI
出版ステータス出版済み - 9 2011
外部発表はい

All Science Journal Classification (ASJC) codes

  • セラミックおよび複合材料
  • 材料化学

フィンガープリント

「Synthesis and characterization of Na<sub>2</sub>Ti<sub>6</sub>O <sub>13</sub> whiskers and their transformation to (1-x) Na<sub>0.5</sub>Bi <sub>0.5</sub>TiO<sub>3</sub>-xBaTiO<sub>3</sub> ceramics」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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