Synthesis and frictional properties of poly(2,3- dihydroxypropylmehtacrylate) brush prepared by surface-initiated atom transfer radical polymerization

Motoyasu Kobayashi, Atsushi Takahara

研究成果: 会議への寄与タイプ論文

抄録

The hydrophobic polymer brush was prepared by surface-initiated atom transfer radical polymerization of (2,2-dimethyl-1,3-dioxolan-4-yl)methyl methacrylate (1) on the initiator-immobilized silicon wafer using copper / sparteine complexes. The contact angle measurements, XPS, and FTIR studies revealed that the amphiphilic poly(2,3-dihyroxypropyl methacrylate) (2) brush was obtained, successively, by acidic hydrolysis of the poly(1) brush. Frictional properties of the poly(1) and (2) brushes were characterized by sliding a stainless or a glass ball probe on the polymer brush surfaces in air and water. Frictional coefficient of poly(2) brush was significantly lowered in water compared with that of poly(1) brush, while poly(2) brush showed larger frictional coefficient than poly(1) brush surface in air.

元の言語英語
ページ数1
出版物ステータス出版済み - 12 1 2005
イベント54th SPSJ Annual Meeting 2005 - Yokohama, 日本
継続期間: 5 25 20055 27 2005

その他

その他54th SPSJ Annual Meeting 2005
日本
Yokohama
期間5/25/055/27/05

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Atom transfer radical polymerization
Brushes
Polymers
Angle measurement
Air
Silicon wafers
Contact angle
Water
Hydrolysis
X ray photoelectron spectroscopy
Copper
Glass

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Synthesis and frictional properties of poly(2,3- dihydroxypropylmehtacrylate) brush prepared by surface-initiated atom transfer radical polymerization. / Kobayashi, Motoyasu; Takahara, Atsushi.

2005. 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本.

研究成果: 会議への寄与タイプ論文

Kobayashi, M & Takahara, A 2005, 'Synthesis and frictional properties of poly(2,3- dihydroxypropylmehtacrylate) brush prepared by surface-initiated atom transfer radical polymerization' 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本, 5/25/05 - 5/27/05, .
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abstract = "The hydrophobic polymer brush was prepared by surface-initiated atom transfer radical polymerization of (2,2-dimethyl-1,3-dioxolan-4-yl)methyl methacrylate (1) on the initiator-immobilized silicon wafer using copper / sparteine complexes. The contact angle measurements, XPS, and FTIR studies revealed that the amphiphilic poly(2,3-dihyroxypropyl methacrylate) (2) brush was obtained, successively, by acidic hydrolysis of the poly(1) brush. Frictional properties of the poly(1) and (2) brushes were characterized by sliding a stainless or a glass ball probe on the polymer brush surfaces in air and water. Frictional coefficient of poly(2) brush was significantly lowered in water compared with that of poly(1) brush, while poly(2) brush showed larger frictional coefficient than poly(1) brush surface in air.",
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