Synthesis and isomerization of N-fused tetraphenylporphyrin ruthenium(II) complexes

Motoki Toganoh, Hideaki Matsuo, Ayumi Sato, Yuya Hirashima, Hiroyuki Furuta

    研究成果: ジャーナルへの寄稿学術誌査読

    13 被引用数 (Scopus)

    抄録

    Three possible isomers of N-fused tetraphenylporphyrin ruthenium complexes, Ru(NFTPp)Cl(CO)2 (2a-c), were isolated and fully characterized by NMR, IR, CV, UV-vis-NIR absorption, and X-ray crystallographic analyses. Each isomer was stable at ambient conditions and isomerization among 2a-c occurred at elevated temperature both in solution and in a solid state, through the intramolecular rotational pathways. Electronic structures of 2a-c were analyzed in detail by DFT study to reveal appreciable differences in the interaction between the NFTPp ligand and the Ru-Cl moiety.

    本文言語英語
    ページ(範囲)9613-9619
    ページ数7
    ジャーナルInorganic chemistry
    52
    16
    DOI
    出版ステータス出版済み - 8月 19 2013

    !!!All Science Journal Classification (ASJC) codes

    • 物理化学および理論化学
    • 無機化学

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