Synthesis and Optical Properties of Thiazolo-Chlorin and Porphyrin Skeletons

Takeo Nakano, Hiroaki Imoto, Kensuke Naka

研究成果: Contribution to journalArticle査読

抄録

Macrocyclic π-skeletons containing a thiazole moiety were synthesized via MacDonald [3 + 1]-type condensation. The construction of thiazolochlorin 1a and thiazoloporphyrin 1b depended on the conformation of the thiazole moieties, and their 18π-systems expanded along the molecular y and x axes, respectively. In particular, the structure of thiazolochlorin 1a was studied in detail using 2D nuclear magnetic resonance methods. The optical properties in solution were measured and discussed based on both experimental data and computational studies.

本文言語英語
ページ(範囲)7996-8000
ページ数5
ジャーナルOrganic letters
23
20
DOI
出版ステータス出版済み - 10 15 2021

All Science Journal Classification (ASJC) codes

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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