Synthesis and photochemical properties of a new molybdenum porphycene complex

Daisuke Maeda, Hisashi Shimakoshi, Masaaki Abe, Yoshio Hisaeda

    研究成果: Contribution to journalArticle査読

    14 被引用数 (Scopus)

    抄録

    A new molybdenum porphycene complex, which is a new complex having oxo and chloro groups at the axial positions, was successfully synthesized. This chloro(oxo)molybdenum(v) complex, [MoV(OEPc)(O)Cl] (1) has strong absorption bands in the visible region attributed to the properties of the porphycene and is very attractive from a photochemical viewpoint. This complex was readily reduced from Mo(v) to Mo(iv) species to yield [Mo IV(OEPc)(O)] under anaerobic irradiation by visible light. This photochemical reaction mechanism is derived from the homolytic cleavage of the axial ligand. Furthermore, this photochemical reduction proceeded very effectively compared to that for the corresponding porphyrin complex.

    本文言語英語
    ページ(範囲)140-145
    ページ数6
    ジャーナルDalton Transactions
    1
    DOI
    出版ステータス出版済み - 1 1 2009

    All Science Journal Classification (ASJC) codes

    • 無機化学

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