Synthesis and properties of a mercapto[15]annulenone: A 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation

Haru Ogawa, Masashi Yoshikawa, Hiroyuki Tanaka, Taiji Imoto, Izumi Miyamoto, Hidefumi Kato, Yoichi Taniguchi, Yasuyoshi Nogami, Toshitaka Koga

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

Mercapto[15]annulenone (4) has been prepared from annulenone (2) as a tautomeric mixture with the keto-tautomer (5) in 65% yield; it was found that (4) proved to be diatropic and exists as a rapid equilibrium mixture of (4a) and (4b).

元の言語英語
ページ(範囲)505-507
ページ数3
ジャーナルJournal of the Chemical Society, Chemical Communications
発行部数8
DOI
出版物ステータス出版済み - 1 1 1989

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Isomerization
Ion exchange
annulenone

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

これを引用

Synthesis and properties of a mercapto[15]annulenone : A 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation. / Ogawa, Haru; Yoshikawa, Masashi; Tanaka, Hiroyuki; Imoto, Taiji; Miyamoto, Izumi; Kato, Hidefumi; Taniguchi, Yoichi; Nogami, Yasuyoshi; Koga, Toshitaka.

:: Journal of the Chemical Society, Chemical Communications, 番号 8, 01.01.1989, p. 505-507.

研究成果: ジャーナルへの寄稿記事

Ogawa, Haru ; Yoshikawa, Masashi ; Tanaka, Hiroyuki ; Imoto, Taiji ; Miyamoto, Izumi ; Kato, Hidefumi ; Taniguchi, Yoichi ; Nogami, Yasuyoshi ; Koga, Toshitaka. / Synthesis and properties of a mercapto[15]annulenone : A 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation. :: Journal of the Chemical Society, Chemical Communications. 1989 ; 番号 8. pp. 505-507.
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AU - Nogami, Yasuyoshi

AU - Koga, Toshitaka

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