Synthesis and Rietveld analysis of Zn4 - XCdxSb 3 bulk crystals in the Zn-rich region

Takeshi Souma, Michitaka Ohtaki

    研究成果: Contribution to journalArticle査読

    14 被引用数 (Scopus)

    抄録

    A series of nine bulk crystals of the Zn4 - xCd xSb3 compounds (x = 0-2.00 with 0.25 step) has been successfully synthesized and the detailed crystal structure has been refined by powder XRD study using the Rietveld method including the quantitative analysis. The substitution limit of the Cd atoms for the Zn4 - xCd xSb3 system has been extended to x = 2.00 by employing the vacuum casting method without annealing. The purities and densities of the bulk crystals exceeded approximately 96 mass% and 95% of XRD density, respectively. The lattice parameters of the a and c-axes in the system increase linearly with increasing Cd content x with obeying the Vegard law.

    本文言語英語
    ページ(範囲)289-297
    ページ数9
    ジャーナルJournal of Alloys and Compounds
    413
    1-2
    DOI
    出版ステータス出版済み - 3 9 2006

    All Science Journal Classification (ASJC) codes

    • 材料力学
    • 機械工学
    • 金属および合金
    • 材料化学

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