TY - JOUR
T1 - Synthesis and spectral and electrochemical properties of 2,3,9,10,16,17,23,24-octabutylthiophthalocyaninatozinc(II)
AU - Takahashi, Kazuhiro
AU - Kawashima, Makoto
AU - Tomita, Yasuhiro
AU - Itoh, Makoto
PY - 1995/1/1
Y1 - 1995/1/1
N2 - The title Zn(II) complex was synthesized, and its UV-Vis electronic absorption spectrum and cyclic voltammograms in N,N-dimethylformamide were measured. The Q and B bands appear around 704 and 370 nm, respectively. The two redox couples indicating reversible one-electron transfer processes appear in the reduction side of the cyclic voltammogram. Adsorption on an electrode surface and irreversible oxidation with decomposition of the complex molecule were confirmed by a controlled-potential electrolysis experiment. The Q and B bands, reduction potentials and oxidation potential of the present complex shift to longer wavelength, positive direction and negative direction, respectively, compared with those of 2,3,9,10,16,17,23,24-octabutoxyphthalocyaninatozinc(II).
AB - The title Zn(II) complex was synthesized, and its UV-Vis electronic absorption spectrum and cyclic voltammograms in N,N-dimethylformamide were measured. The Q and B bands appear around 704 and 370 nm, respectively. The two redox couples indicating reversible one-electron transfer processes appear in the reduction side of the cyclic voltammogram. Adsorption on an electrode surface and irreversible oxidation with decomposition of the complex molecule were confirmed by a controlled-potential electrolysis experiment. The Q and B bands, reduction potentials and oxidation potential of the present complex shift to longer wavelength, positive direction and negative direction, respectively, compared with those of 2,3,9,10,16,17,23,24-octabutoxyphthalocyaninatozinc(II).
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U2 - 10.1016/0020-1693(94)04385-9
DO - 10.1016/0020-1693(94)04385-9
M3 - Article
AN - SCOPUS:0010291721
VL - 232
SP - 69
EP - 73
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1-2
ER -