Synthesis and structure of a water-soluble μ-η1: η1-N2 dinuclear RuII complex with a polyamine ligand

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Andrew Robertson, Hidetaka Nakai, Hiromasa Tanaka, Takashi Kamachi, Yoshihito Shiota, Kazunari Yoshizawa, Koichiro Asazawa, Hirohisa Tanaka, Seiji Ogo

研究成果: ジャーナルへの寄稿記事

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We report the first example of a μ-η11-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

元の言語英語
ページ(範囲)149-151
ページ数3
ジャーナルChemistry Letters
45
発行部数2
DOI
出版物ステータス出版済み - 1 1 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント Synthesis and structure of a water-soluble μ-η<sup>1</sup>: η<sup>1</sup>-N<sub>2</sub> dinuclear Ru<sup>II</sup> complex with a polyamine ligand' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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