Synthesis and structure of a water-soluble μ-η1

η1-N2 dinuclear RuII complex with a polyamine ligand

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Andrew Robertson, Hidetaka Nakai, Hiromasa Tanaka, Takashi Kamachi, Yoshihito Shiota, Kazunari Yoshizawa, Koichiro Asazawa, Hirohisa Tanaka, Seiji Ogo

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

We report the first example of a μ-η11-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

元の言語英語
ページ(範囲)149-151
ページ数3
ジャーナルChemistry Letters
45
発行部数2
DOI
出版物ステータス出版済み - 1 1 2016

Fingerprint

X ray analysis
Polyamines
Stretching
Raman spectroscopy
Chemical activation
Ligands
Water

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

Synthesis and structure of a water-soluble μ-η1 : η1-N2 dinuclear RuII complex with a polyamine ligand. / Yoshimoto, Koji; Yatabe, Takeshi; Matsumoto, Takahiro; Robertson, Andrew; Nakai, Hidetaka; Tanaka, Hiromasa; Kamachi, Takashi; Shiota, Yoshihito; Yoshizawa, Kazunari; Asazawa, Koichiro; Tanaka, Hirohisa; Ogo, Seiji.

:: Chemistry Letters, 巻 45, 番号 2, 01.01.2016, p. 149-151.

研究成果: ジャーナルへの寄稿記事

Yoshimoto, Koji ; Yatabe, Takeshi ; Matsumoto, Takahiro ; Robertson, Andrew ; Nakai, Hidetaka ; Tanaka, Hiromasa ; Kamachi, Takashi ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Asazawa, Koichiro ; Tanaka, Hirohisa ; Ogo, Seiji. / Synthesis and structure of a water-soluble μ-η1 : η1-N2 dinuclear RuII complex with a polyamine ligand. :: Chemistry Letters. 2016 ; 巻 45, 番号 2. pp. 149-151.
@article{b81b89c2f9c540cb8d4b4e3b914df9b6,
title = "Synthesis and structure of a water-soluble μ-η1: η1-N2 dinuclear RuII complex with a polyamine ligand",
abstract = "We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.",
author = "Koji Yoshimoto and Takeshi Yatabe and Takahiro Matsumoto and Andrew Robertson and Hidetaka Nakai and Hiromasa Tanaka and Takashi Kamachi and Yoshihito Shiota and Kazunari Yoshizawa and Koichiro Asazawa and Hirohisa Tanaka and Seiji Ogo",
year = "2016",
month = "1",
day = "1",
doi = "10.1246/cl.151004",
language = "English",
volume = "45",
pages = "149--151",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "2",

}

TY - JOUR

T1 - Synthesis and structure of a water-soluble μ-η1

T2 - η1-N2 dinuclear RuII complex with a polyamine ligand

AU - Yoshimoto, Koji

AU - Yatabe, Takeshi

AU - Matsumoto, Takahiro

AU - Robertson, Andrew

AU - Nakai, Hidetaka

AU - Tanaka, Hiromasa

AU - Kamachi, Takashi

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Asazawa, Koichiro

AU - Tanaka, Hirohisa

AU - Ogo, Seiji

PY - 2016/1/1

Y1 - 2016/1/1

N2 - We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

AB - We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

UR - http://www.scopus.com/inward/record.url?scp=84958987764&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84958987764&partnerID=8YFLogxK

U2 - 10.1246/cl.151004

DO - 10.1246/cl.151004

M3 - Article

VL - 45

SP - 149

EP - 151

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 2

ER -