Synthesis and structure of protic amine tethered rhodium(III) peralkylcyclopentadienyl complexes

Masato Ito; Noriko Tejima; Masahiro Yamamura; Yoshinori Endo; Takao Ikariya

doi:10.1021/om100151m

Synthesis and structure of protic amine tethered rhodium(III) peralkylcyclopentadienyl complexes

Masato Ito, Noriko Tejima, Masahiro Yamamura, Yoshinori Endo, Takao Ikariya

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

10 被引用数 (Scopus)

抄録

A series of mononuclear tethered complexes, Rh^III(η ⁵:η¹-Cp--NHR), in which the η⁵- peralkylcyclopentadienyl group and the ligated protic amine group are connected by suitable carbon chains, were newly prepared and structurally characterized. Their catalytic performance in the reductive amination of carbonyl compounds was significantly influenced by the chain length of the tether, which possibly plays a key role in determining the reaction course.

本文言語	英語
ページ（範囲）	1886-1889
ページ数	4
ジャーナル	Organometallics
巻	29
号	8
DOI	https://doi.org/10.1021/om100151m
出版ステータス	出版済み - 4月 26 2010

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
有機化学
無機化学

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10.1021/om100151m

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title = "Synthesis and structure of protic amine tethered rhodium(III) peralkylcyclopentadienyl complexes",

abstract = "A series of mononuclear tethered complexes, RhIII(η 5:η1-Cp--NHR), in which the η5- peralkylcyclopentadienyl group and the ligated protic amine group are connected by suitable carbon chains, were newly prepared and structurally characterized. Their catalytic performance in the reductive amination of carbonyl compounds was significantly influenced by the chain length of the tether, which possibly plays a key role in determining the reaction course.",

author = "Masato Ito and Noriko Tejima and Masahiro Yamamura and Yoshinori Endo and Takao Ikariya",

year = "2010",

month = apr,

day = "26",

doi = "10.1021/om100151m",

language = "English",

volume = "29",

pages = "1886--1889",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis and structure of protic amine tethered rhodium(III) peralkylcyclopentadienyl complexes

AU - Ito, Masato

AU - Tejima, Noriko

AU - Yamamura, Masahiro

AU - Endo, Yoshinori

AU - Ikariya, Takao

PY - 2010/4/26

Y1 - 2010/4/26

N2 - A series of mononuclear tethered complexes, RhIII(η 5:η1-Cp--NHR), in which the η5- peralkylcyclopentadienyl group and the ligated protic amine group are connected by suitable carbon chains, were newly prepared and structurally characterized. Their catalytic performance in the reductive amination of carbonyl compounds was significantly influenced by the chain length of the tether, which possibly plays a key role in determining the reaction course.

AB - A series of mononuclear tethered complexes, RhIII(η 5:η1-Cp--NHR), in which the η5- peralkylcyclopentadienyl group and the ligated protic amine group are connected by suitable carbon chains, were newly prepared and structurally characterized. Their catalytic performance in the reductive amination of carbonyl compounds was significantly influenced by the chain length of the tether, which possibly plays a key role in determining the reaction course.

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UR - http://www.scopus.com/inward/citedby.url?scp=77951125774&partnerID=8YFLogxK

U2 - 10.1021/om100151m

DO - 10.1021/om100151m

M3 - Article

AN - SCOPUS:77951125774

VL - 29

SP - 1886

EP - 1889

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 8

ER -

Synthesis and structure of protic amine tethered rhodium(III) peralkylcyclopentadienyl complexes

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!!!All Science Journal Classification (ASJC) codes

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