Synthesis of 2,6,9-substituted xanthen-3-one and solvent effect on structural and photophysical properties

Taro Koide; Shohei Iwamori; Satoshi Koga; Yasutaka Suzuki; Jun Kawamata; Yoshio Hisaeda

doi:10.1016/j.dyepig.2020.108667

Synthesis of 2,6,9-substituted xanthen-3-one and solvent effect on structural and photophysical properties

Taro Koide, Shohei Iwamori, Satoshi Koga, Yasutaka Suzuki, Jun Kawamata, Yoshio Hisaeda

総長・役員等

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

3 被引用数 (Scopus)

抄録

The synthesis of donor-π-donor type 2,6,9-substituted xanthen-3-one and its solvent effect on both the structural and photophysical properties were revealed. The keto-enol isomerization behavior and red-shift of the emission wavelengths were observed depending on the solvent polarity. This observation indicated that twisted intramolecular charge transfer (TICT) occurs in this system. This is probably due to the electron donating aryl group at 2-position of the xanthene skeleton, which could rotate in the excited state. The luminescence of the compound was also confirmed in a living cell.

本文言語	英語
論文番号	108667
ジャーナル	Dyes and Pigments
巻	183
DOI	https://doi.org/10.1016/j.dyepig.2020.108667
出版ステータス	出版済み - 12月 2020

!!!All Science Journal Classification (ASJC) codes

化学工学（全般）
プロセス化学およびプロセス工学

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10.1016/j.dyepig.2020.108667

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title = "Synthesis of 2,6,9-substituted xanthen-3-one and solvent effect on structural and photophysical properties",

abstract = "The synthesis of donor-π-donor type 2,6,9-substituted xanthen-3-one and its solvent effect on both the structural and photophysical properties were revealed. The keto-enol isomerization behavior and red-shift of the emission wavelengths were observed depending on the solvent polarity. This observation indicated that twisted intramolecular charge transfer (TICT) occurs in this system. This is probably due to the electron donating aryl group at 2-position of the xanthene skeleton, which could rotate in the excited state. The luminescence of the compound was also confirmed in a living cell.",

author = "Taro Koide and Shohei Iwamori and Satoshi Koga and Yasutaka Suzuki and Jun Kawamata and Yoshio Hisaeda",

note = "Funding Information: This work was partially supported by JSPS KAKENHI Grant Number JP19K22204 , 19K05403 , 19H04677 . T. K. is grateful for the financial support from Tonen General Sekiyu , Casio Science Promotion Foundation and Kyushu University . Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1016/j.dyepig.2020.108667",

language = "English",

volume = "183",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Synthesis of 2,6,9-substituted xanthen-3-one and solvent effect on structural and photophysical properties

AU - Koide, Taro

AU - Iwamori, Shohei

AU - Koga, Satoshi

AU - Suzuki, Yasutaka

AU - Kawamata, Jun

AU - Hisaeda, Yoshio

N1 - Funding Information: This work was partially supported by JSPS KAKENHI Grant Number JP19K22204 , 19K05403 , 19H04677 . T. K. is grateful for the financial support from Tonen General Sekiyu , Casio Science Promotion Foundation and Kyushu University . Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - The synthesis of donor-π-donor type 2,6,9-substituted xanthen-3-one and its solvent effect on both the structural and photophysical properties were revealed. The keto-enol isomerization behavior and red-shift of the emission wavelengths were observed depending on the solvent polarity. This observation indicated that twisted intramolecular charge transfer (TICT) occurs in this system. This is probably due to the electron donating aryl group at 2-position of the xanthene skeleton, which could rotate in the excited state. The luminescence of the compound was also confirmed in a living cell.

AB - The synthesis of donor-π-donor type 2,6,9-substituted xanthen-3-one and its solvent effect on both the structural and photophysical properties were revealed. The keto-enol isomerization behavior and red-shift of the emission wavelengths were observed depending on the solvent polarity. This observation indicated that twisted intramolecular charge transfer (TICT) occurs in this system. This is probably due to the electron donating aryl group at 2-position of the xanthene skeleton, which could rotate in the excited state. The luminescence of the compound was also confirmed in a living cell.

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U2 - 10.1016/j.dyepig.2020.108667

DO - 10.1016/j.dyepig.2020.108667

M3 - Article

AN - SCOPUS:85089381448

VL - 183

JO - Dyes and Pigments

JF - Dyes and Pigments

SN - 0143-7208

M1 - 108667

ER -

Synthesis of 2,6,9-substituted xanthen-3-one and solvent effect on structural and photophysical properties

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!!!All Science Journal Classification (ASJC) codes

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