Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry

Seiji Ogo; Takayoshi Suzuki; Sachiyo Nomura; Kiyotaka Asakura; Kiyoshi Isobe

doi:10.1007/BF01165471

Synthesis of a linear-type pentanuclear (Rh^III-W^VI-Cu^I-W^VI-Rh^III) sulfide cluster predicted by fast atom bombardment mass spectrometry

Seiji Ogo, Takayoshi Suzuki, Sachiyo Nomura, Kiyotaka Asakura, Kiyoshi Isobe

研究成果: Contribution to journal › Article › 査読

3 被引用数 (Scopus)

抄録

The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp^*RhP(OEt)₃(μ-WS₄CuCl] (1; Cp^* = η⁵-C₅Me₅), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp^*RhP(OEt)₃(WS₄)}₂Cu]⁺. It has been synthesized by a reaction between [Cp^*RhP(OEt)₃WS₄] and Cu⁺ in a 2:1 molar ratio as the PF₆ salt [{Cp^*RhP(OEt)₃(μ-WS₄)}₂Cu][PF₆] (2 · PF₆), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.

本文言語	英語
ページ（範囲）	421-436
ページ数	16
ジャーナル	Journal of Cluster Science
巻	6
号	3
DOI	https://doi.org/10.1007/BF01165471
出版ステータス	出版済み - 9 1 1995
外部発表	はい

All Science Journal Classification (ASJC) codes

生化学
化学 (全般)
材料科学（全般）
凝縮系物理学

文献へのアクセス

10.1007/BF01165471

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引用スタイル

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title = "Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry",

abstract = "The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.",

author = "Seiji Ogo and Takayoshi Suzuki and Sachiyo Nomura and Kiyotaka Asakura and Kiyoshi Isobe",

year = "1995",

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T1 - Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry

AU - Ogo, Seiji

AU - Suzuki, Takayoshi

AU - Nomura, Sachiyo

AU - Asakura, Kiyotaka

AU - Isobe, Kiyoshi

PY - 1995/9/1

Y1 - 1995/9/1

N2 - The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.

AB - The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.

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