抄録
The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 421-436 |
| ページ数 | 16 |
| ジャーナル | Journal of Cluster Science |
| 巻 | 6 |
| 発行部数 | 3 |
| DOI | |
| 出版物ステータス | 出版済み - 9 1 1995 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Biochemistry
- Materials Science(all)
- Condensed Matter Physics
これを引用
Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry. / Ogo, Seiji; Suzuki, Takayoshi; Nomura, Sachiyo; Asakura, Kiyotaka; Isobe, Kiyoshi.
：: Journal of Cluster Science, 巻 6, 番号 3, 01.09.1995, p. 421-436.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry
AU - Ogo, Seiji
AU - Suzuki, Takayoshi
AU - Nomura, Sachiyo
AU - Asakura, Kiyotaka
AU - Isobe, Kiyoshi
PY - 1995/9/1
Y1 - 1995/9/1
N2 - The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.
AB - The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.
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U2 - 10.1007/BF01165471
DO - 10.1007/BF01165471
M3 - Article
AN - SCOPUS:2542453278
VL - 6
SP - 421
EP - 436
JO - Journal of Cluster Science
JF - Journal of Cluster Science
SN - 1040-7278
IS - 3
ER -