Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry

Seiji Ogo, Takayoshi Suzuki, Sachiyo Nomura, Kiyotaka Asakura, Kiyoshi Isobe

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.

元の言語英語
ページ(範囲)421-436
ページ数16
ジャーナルJournal of Cluster Science
6
発行部数3
DOI
出版物ステータス出版済み - 9 1 1995

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Fast Atom Bombardment Mass Spectrometry
Heavy Ions
Sulfides
Heavy ions
Mass spectrometry
bombardment
sulfides
mass spectroscopy
Salts
Positive ions
Single crystals
Ions
X ray diffraction
Atoms
FORTRAN
synthesis
molecular ions
positive ions
X-Ray Diffraction
mass spectra

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry
  • Materials Science(all)
  • Condensed Matter Physics

これを引用

Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry. / Ogo, Seiji; Suzuki, Takayoshi; Nomura, Sachiyo; Asakura, Kiyotaka; Isobe, Kiyoshi.

:: Journal of Cluster Science, 巻 6, 番号 3, 01.09.1995, p. 421-436.

研究成果: ジャーナルへの寄稿記事

Ogo, Seiji ; Suzuki, Takayoshi ; Nomura, Sachiyo ; Asakura, Kiyotaka ; Isobe, Kiyoshi. / Synthesis of a linear-type pentanuclear (RhIII-WVI-CuI-WVI-RhIII) sulfide cluster predicted by fast atom bombardment mass spectrometry. :: Journal of Cluster Science. 1995 ; 巻 6, 番号 3. pp. 421-436.
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abstract = "The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.",
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AU - Suzuki, Takayoshi

AU - Nomura, Sachiyo

AU - Asakura, Kiyotaka

AU - Isobe, Kiyoshi

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