Synthesis of acetic acid from CO2, CH3I and H2using a water-soluble electron storage catalyst

Takeshi Yatabe, Kazuki Kamitakahara, Kaede Higashijima, Tatsuya Ando, Takahiro Matsumoto, Ki Seok Yoon, Takao Enomoto, Seiji Ogo

研究成果: Contribution to journalArticle査読

抄録

This paper reports a possible mechanism of acetic acid formation from CO2, CH3I and H2in aqueous media and the central role played by a water-soluble Rh-based electron storage catalyst. In addition to water-solubility, we also report the crystal structures of two presumed intermediates. These findings together reveal (1) the advantage of water, not only as a green solvent, but also as a reactive Lewis base to extract H+from H2, (2) the role of the metal (Rh) centre as a point for storing electrons from H2and (3) the importance of an electron-withdrawing ligand (quaterpyridine, qpy) that supports electron storage.

本文言語英語
ページ(範囲)4772-4774
ページ数3
ジャーナルChemical Communications
57
39
DOI
出版ステータス出版済み - 5 14 2021

All Science Journal Classification (ASJC) codes

  • 触媒
  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • 化学 (全般)
  • 表面、皮膜および薄膜
  • 金属および合金
  • 材料化学

フィンガープリント

「Synthesis of acetic acid from CO<sub>2</sub>, CH<sub>3</sub>I and H<sub>2</sub>using a water-soluble electron storage catalyst」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル