Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe, Takahiro Kikunaga, Takahiro Matsumoto, Hidetaka Nakai, Ki Seok Yoon, Seiji Ogo

研究成果: Contribution to journalArticle

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We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

元の言語英語
ページ(範囲)1380-1382
ページ数3
ジャーナルChemistry Letters
43
発行部数8
DOI
出版物ステータス出版済み - 1 1 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント Synthesis of aqueous-stable and water-soluble mononuclear nonheme Mn<sup>V</sup>-Oxo complexes using H<sub>2</sub>O<sub>2</sub>as an oxidant' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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