Synthesis of CH 2 -Linked α(1,6)-Disaccharide Analogues by α-Selective Radical Coupling C-Glycosylation

Noriaki Kiya, Yu Hidaka, Kazuteru Usui, Go Hirai

研究成果: ジャーナルへの寄稿記事

3 引用 (Scopus)

抜粋

C-Linked carbohydrate structure, in which the cleavable O-glycosidic linkage is replaced by a carbon unit, is a useful tool for functional analyses of glycoconjugates. We describe a synthetic method for α-CH 2 -linked disaccharide structures, such as Glc(1,6)-Glc, by stereoselective radical-coupling C-glycosylation between a conformationally constrained and stable C1-sp 3 hybridized xanthate donor and a carefully designed acceptor.

元の言語英語
ページ(範囲)1588-1592
ページ数5
ジャーナルOrganic letters
21
発行部数6
DOI
出版物ステータス出版済み - 3 15 2019

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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