Synthesis of Cp-Re complexes via olefinic C-H activation and successive formation of cyclopentadienes

Yoichiro Kuninobu, Yuta Nishina, Takashi Matsuki, Kazuhiko Takai

研究成果: Contribution to journalArticle査読

42 被引用数 (Scopus)

抄録

Treatment of an α,β-unsaturated ketimine with an α,β-unsaturated carbonyl compound in the presence of a rhenium complex, Re2(CO)10, gave a cyclopentadienyl-rhenium complex. This reaction proceeds via rhenium-catalyzed C-H bond activation of an olefinic C-H bond, insertion of an α,β-unsaturated carbonyl compound into a Re-C bond of the alkenylrhenium intermediate, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline to give a cyclopentadiene derivative, followed by the formation of a cyclopentadienyl-rhenium complex from the cyclopentadiene derivative and the rhenium complex.

本文言語英語
ページ(範囲)14062-14063
ページ数2
ジャーナルJournal of the American Chemical Society
130
43
DOI
出版ステータス出版済み - 10 29 2008
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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