Synthesis of inorganic-organic hybrid membranes consisting of triazole linkages formed by the azide-alkyne click reaction

Naoya Ozawa, Koichiro Hayashi, Shin ichi Yamaura, Wei Zhang, Wataru Sakamoto, Toshinobu Yogo

研究成果: ジャーナルへの寄稿記事

6 引用 (Scopus)

抄録

Inorganic-organic hybrid membranes consisting of aliphatic main chains and triazole rings were synthesized via copolymerization of a methacryloxysiloxane derivative with phosphonic acrylate, followed by hydrolysis. Hydroxyethyl methacrylate acid phosphate (HEMAP) was copolymerized with 3-methacryloxypropylmethyl-dimethoxysilane (MPMDMS), and then reacted with diethyl (4-(1-(3-(trimethoxysilyl)propyl)-1,2,3-triazol-4-yl)phenyl)phosphonate (TMSTAzPP), yielding inorganic-organic hybrid composites. The triazole ring of TMSTAzPP was constructed via the azide-alkyne click reaction using nanoporous Cu. IR, 13C, and 29Si NMR spectroscopy supported the formation of the inorganic-organic hybrid structure including a triazole ring. The membranes showed good thermal stability up to 180 °C. The conductivity of the HEMAP/MPMDMS/TMSTAzPP membrane with a composition of 7:1:3 was higher than that of the HEMAP/MPMDMS membrane with a composition of 10:1. The conductivities of the 12:1:3 membranes at 130 °C were 1.05×10−1 S cm−1 and 1.68×10−4 S cm−1 at 100% and 19.3% relative humidities (RHs), respectively. The power density of the 12:1:3 membrane was 3.9 mW cm−2 at 140 °C and 30% RH.

元の言語英語
ページ(範囲)21-29
ページ数9
ジャーナルJournal of Membrane Science
517
DOI
出版物ステータス出版済み - 11 1 2016

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Synthetic Chemistry Techniques
Triazoles
Alkynes
Azides
alkynes
linkages
membranes
Membranes
Organophosphonates
synthesis
phosphates
Phosphates
Humidity
acids
Acids
humidity
rings
Atmospheric humidity
hybrid composites
conductivity

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

これを引用

Synthesis of inorganic-organic hybrid membranes consisting of triazole linkages formed by the azide-alkyne click reaction. / Ozawa, Naoya; Hayashi, Koichiro; Yamaura, Shin ichi; Zhang, Wei; Sakamoto, Wataru; Yogo, Toshinobu.

:: Journal of Membrane Science, 巻 517, 01.11.2016, p. 21-29.

研究成果: ジャーナルへの寄稿記事

Ozawa, Naoya ; Hayashi, Koichiro ; Yamaura, Shin ichi ; Zhang, Wei ; Sakamoto, Wataru ; Yogo, Toshinobu. / Synthesis of inorganic-organic hybrid membranes consisting of triazole linkages formed by the azide-alkyne click reaction. :: Journal of Membrane Science. 2016 ; 巻 517. pp. 21-29.
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abstract = "Inorganic-organic hybrid membranes consisting of aliphatic main chains and triazole rings were synthesized via copolymerization of a methacryloxysiloxane derivative with phosphonic acrylate, followed by hydrolysis. Hydroxyethyl methacrylate acid phosphate (HEMAP) was copolymerized with 3-methacryloxypropylmethyl-dimethoxysilane (MPMDMS), and then reacted with diethyl (4-(1-(3-(trimethoxysilyl)propyl)-1,2,3-triazol-4-yl)phenyl)phosphonate (TMSTAzPP), yielding inorganic-organic hybrid composites. The triazole ring of TMSTAzPP was constructed via the azide-alkyne click reaction using nanoporous Cu. IR, 13C, and 29Si NMR spectroscopy supported the formation of the inorganic-organic hybrid structure including a triazole ring. The membranes showed good thermal stability up to 180 °C. The conductivity of the HEMAP/MPMDMS/TMSTAzPP membrane with a composition of 7:1:3 was higher than that of the HEMAP/MPMDMS membrane with a composition of 10:1. The conductivities of the 12:1:3 membranes at 130 °C were 1.05×10−1 S cm−1 and 1.68×10−4 S cm−1 at 100{\%} and 19.3{\%} relative humidities (RHs), respectively. The power density of the 12:1:3 membrane was 3.9 mW cm−2 at 140 °C and 30{\%} RH.",
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AU - Yogo, Toshinobu

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