Synthesis of Optically Active 1,3,2-Oxazaphospholidine 2-Sulfides and 1,3,2-Benzodioxaphosphorin 2-Sulfides

Shao Yong Wu, Akinori Hirashima, Eiichi Kuwano, Morifusa Eto

研究成果: ジャーナルへの寄稿記事

抄録

The optical isomers of ten kinds of insecticidal 1,3,2-oxazaphospholidine 2-sulfides (OS) and two kinds of 1,3,2-benzodioxaphosphorin 2-sulfides (BS), including the commercial insecticide salithion, were synthesized in high optical purity by using two optically active aryl methyl phosphorochloridothionates (AMPC) as chiral two-step phosphorylating reagents. Their configurations were assigned according to the reaction mechanisms and supported by proton NMR information.

元の言語英語
ページ(範囲)537-547
ページ数11
ジャーナルAgricultural and Biological Chemistry
51
発行部数2
DOI
出版物ステータス出版済み - 1 1 1987

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Sulfides
sulfides
synthesis
reaction mechanisms
Insecticides
Isomers
purity
protons
isomers
Protons
insecticides
Nuclear magnetic resonance
(1,3,2)oxazaphospholidine
salithion

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)
  • Agricultural and Biological Sciences(all)

これを引用

Synthesis of Optically Active 1,3,2-Oxazaphospholidine 2-Sulfides and 1,3,2-Benzodioxaphosphorin 2-Sulfides. / Wu, Shao Yong; Hirashima, Akinori; Kuwano, Eiichi; Eto, Morifusa.

:: Agricultural and Biological Chemistry, 巻 51, 番号 2, 01.01.1987, p. 537-547.

研究成果: ジャーナルへの寄稿記事

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