Synthesis of Optically Active 1,3,2-Oxazaphospholidine 2-Sulfides and 1,3,2-Benzodioxaphosphorin 2-Sulfides

Shao Yong Wu, Akinori Hirashima, Eiichi Kuwano, Morifusa Eto

研究成果: ジャーナルへの寄稿学術誌査読

抄録

The optical isomers of ten kinds of insecticidal 1,3,2-oxazaphospholidine 2-sulfides (OS) and two kinds of 1,3,2-benzodioxaphosphorin 2-sulfides (BS), including the commercial insecticide salithion, were synthesized in high optical purity by using two optically active aryl methyl phosphorochloridothionates (AMPC) as chiral two-step phosphorylating reagents. Their configurations were assigned according to the reaction mechanisms and supported by proton NMR information.

本文言語英語
ページ(範囲)537-547
ページ数11
ジャーナルAgricultural and Biological Chemistry
51
2
DOI
出版ステータス出版済み - 1987

!!!All Science Journal Classification (ASJC) codes

  • 生化学、遺伝学、分子生物学(全般)
  • 農業および生物科学(全般)

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