Synthesis of optically active cyclic phosphorothionates and phosphoramidothionates with insecticidal activityby using a chiral phosphorylating agent

Akinori Hirashima, Morifusa Eto

研究成果: Contribution to journalArticle査読

29 被引用数 (Scopus)

抄録

Chiral methyl/7-nitrophenyl phosphorochloridothionate (MNPC) was utilized as a phosphorylating agent in the synthesis of optically active cyclic phosphorus esters including the enantiomers of 2-methoxy-4#-l, 3, 2-benzodioxaphosphorin 2-sulfide (salithion) and four diastereomers of 4-isobutyl-2-methoxy-l, 3, 2-oxazaphospholidine 2-sulfide (BMOS). Their insecticidal activity decreased in the following order; (S) > (R) in salithion and (S)P(S)C > (S)P(R)C > (R)P(R)C >(R)P(S)C in BMOS.

本文言語英語
ページ(範囲)2831-2839
ページ数9
ジャーナルAgricultural and Biological Chemistry
47
12
DOI
出版ステータス出版済み - 12 1983

All Science Journal Classification (ASJC) codes

  • 生化学、遺伝学、分子生物学(全般)
  • 農業および生物科学(全般)

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