Synthesis of pentamethyl-monohydro[60]fullerene C60Me5H and its use as cyclopentadienyl-type ligand precursor

Masaya Sawamura; Motoki Toganoh; Yoichiro Kuninobu; Seiichi Kato; Eiichi Nakamura

doi:10.1246/cl.2000.270

Synthesis of pentamethyl-monohydro[60]fullerene C₆₀Me₅H and its use as cyclopentadienyl-type ligand precursor

Masaya Sawamura, Motoki Toganoh, Yoichiro Kuninobu, Seiichi Kato, Eiichi Nakamura

研究成果: Contribution to journal › Article › 査読

14 被引用数 (Scopus)

抄録

Pentamethyl-monohydro[60]fullerene C₆₀Me₅H has been synthesized through five-fold addition of methyleopper reagent to C₆₀. The anion C₆₀Me₅ generated by deprotonation of C₆₀Me₅H forms organometallic complexes with K⁺ and Tl⁺ ions with stronger metal-carbon interaction than that in the corresponding pentaphenylated ligand C₆₀Ph₅ ⁺.

本文言語	英語
ページ（範囲）	270-271
ページ数	2
ジャーナル	Chemistry Letters
号	3
DOI	https://doi.org/10.1246/cl.2000.270
出版ステータス	出版済み - 1 1 2000
外部発表	はい

All Science Journal Classification (ASJC) codes

Chemistry(all)

文献へのアクセス

10.1246/cl.2000.270

フィンガープリント「Synthesis of pentamethyl-monohydro[60]fullerene C<sub>60</sub>Me<sub>5</sub>H and its use as cyclopentadienyl-type ligand precursor」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "Pentamethyl-monohydro[60]fullerene C60Me5H has been synthesized through five-fold addition of methyleopper reagent to C60. The anion C60Me5 generated by deprotonation of C60Me5H forms organometallic complexes with K+ and Tl+ ions with stronger metal-carbon interaction than that in the corresponding pentaphenylated ligand C60Ph5 +.",

author = "Masaya Sawamura and Motoki Toganoh and Yoichiro Kuninobu and Seiichi Kato and Eiichi Nakamura",

year = "2000",

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doi = "10.1246/cl.2000.270",

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AU - Kuninobu, Yoichiro

AU - Kato, Seiichi

AU - Nakamura, Eiichi

PY - 2000/1/1

Y1 - 2000/1/1

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AB - Pentamethyl-monohydro[60]fullerene C60Me5H has been synthesized through five-fold addition of methyleopper reagent to C60. The anion C60Me5 generated by deprotonation of C60Me5H forms organometallic complexes with K+ and Tl+ ions with stronger metal-carbon interaction than that in the corresponding pentaphenylated ligand C60Ph5 +.

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